18 January, 2009

Lead

Lead is not found free in nature but Galena (lead sulfide) was used as an eye paint by the ancient Egyptians. Galena has a very metallic looking appearance and was, therefore, likely to attract the attention of early metalworkers. The production of metallic lead from its ore is relatively easy and could have been produced by reduction of Galena in a camp fire. The melting point of lead is 327 C, therefore, it would easily flow to the lowest point in the fireplace and collect. At first lead was not used widely because it was too ductile and the first uses of lead were around 3500 B.C.. Lead's use as a container and conduit was important and lead pipes bearing the insignia of Roman emperors can still be found. Lead is highly malleable, ductile and noncorrosive making it an excellent piping material. Its symbol is Pb from the latin plumbum. The ability of lead to flow and collect at the bottom of the campfire is an important concept in process metallurgy as reduction reactions to be useful must cause a phase separation between the metal and the gangue. Also, the phase separation should also enable the metal to be cast into a desired shape once concentrated